RESEARCH OF BUILDING MATERIALS

Using rice straw to manufacture ceramic bricks

Vestnik MGSU 11/2014
  • Gorbunov German Ivanovich - Moscow State University of Civil Engineering (MGSU) Candidate of Technical Sciences, Professor, Department of Technology of Finishing and Insulation Materials, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation; This e-mail address is being protected from spambots. You need JavaScript enabled to view it .
  • Rasulov Olimdzhon Rakhmonberdievich - Moscow State University of Civil Engineering (MGSU) postgraduate student, Department of Technology of Finishing and Insulation Materials, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation; This e-mail address is being protected from spambots. You need JavaScript enabled to view it .

Pages 128-136

In the article, the co-authors offer their advanced and efficient methodologies for the recycling of the rice straw, as well as the novel approaches to the ceramic brick quality improvement through the application of the rice straw as the combustible additive and through the formation of amorphous silica in the course of the rice straw combustion. The co-authors provide characteristics of the raw materials, production techniques used to manufacture ceramic bricks, and their basic properties in the article. The co-authors describe the simulated process of formation of amorphous silica. The process in question has two independent steps (or options): 1) rice straw combustion and ash formation outside the oven (in the oxidizing medium), and further application of ash as the additive in the process of burning clay mixtures; 2) adding pre-treated rice straw as the combustible additive into the clay mixture, and its further burning in compliance with the pre-set temperature mode. The findings have proven that the most rational pre-requisite of the rice straw application in the manufacturing of ceramic bricks consists in feeding milled straw into the clay mixture to be followed by molding, drying and burning. Brick samples are highly porous, and they also demonstrate sufficient compressive strength. The co-authors have also identified optimal values of rice straw and ash content in the mixtures under research.

DOI: 10.22227/1997-0935.2014.11.128-136

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Fire hazard of phosphorus-containing hard casting polyurethane foams

Vestnik MGSU 12/2018 Volume 13
  • Ushkov Valentin A. - Moscow State University of Civil Engineering (National Research University) (MGSU) , Moscow State University of Civil Engineering (National Research University) (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation.
  • Sokoreva Evgeniya V. - Moscow State University of Civil Engineering (National Research University) (MGSU) , Moscow State University of Civil Engineering (National Research University) (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation.
  • Goryunova Anna V. - Moscow State University of Civil Engineering (National Research University) (MGSU) , Moscow State University of Civil Engineering (National Research University) (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation.
  • Demjanenko Stanislav A. - Moscow State University of Civil Engineering (National Research University) (MGSU) , Moscow State University of Civil Engineering (National Research University) (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation.

Pages 1524-1532

Introduction. Fire-safe rigid filling polyurethane foams (PUF), meant for low-temperature thermal insulation of pipelines and technological equipment were developed. The effect of concentration of oxyethylated tetraalkylphosphonate pentaerythritol (phostetrol-1) on technological, physico-mechanical and thermal properties, contents of pyrolysis products and main fire hazard indicators of PUFs was explored. The effect of chemical nature and metal compounds concentration of variable valence on fume-generation ability of phosphorous-containing PUFs was examined. Main technological and physico-mechanical properties and fire hazard indicators of developed styrofoams are provided. Materials and methods. Rigid filling PUFs were obtained on the basis of simple oxyethylated polyols and polyisocyanate. Phostetrol-1 was used as a reactive phosphorous-containing compound. As a foaming and hardening catalyst of developed PUF’s a nitrogen-containing polyol (mark Lapromol 294) and dimethylethanolamine was used, and as a foaming agent - mixture of freon - 11 and water. Different metal compounds of variable valence were used to reduce fume-generation ability and toxicity of pyrolysis products of rigid phosphorous-containing PUFs. Thermal properties of examined PUFs were studied with the help of thermoanalytical complex Du PONT 9000. Main technological and physico-mechanical properties and fire hazard indicators of styrofoams were determined under existing GOSTs. Results. The effect of phostetrol-1 concentration in polyester compound on main technological and physico-mechanical properties, contents of pyrolysis products and main fire hazard indicators of rigid filling PUFs was established. It is shown that to obtain moderately flammable PUFs the phosphorous concentration in styrofoam must exceed 2.5 mass. %. The correlation between low-scale evaluation methods of flammability of rigid PUFs was found. The effect of phosphorous concentration on fume-generation ability and contents of pyrolysis products of rigid PUFs was found. The effect of chemical nature and metal compounds concentration of variable valence on fume-generation ability of phosphorous-containing PUFs was examined. It is shown that effective decrease of fume-generation ability and toxicity of pyrolysis products of moderately flammable PUFs occurs when Cu2O or chrome spinels are introduced to the polyester compound. Conclusions. As a result of conducted research it was established that the combined use of phostetrol-1, Cu2O and chrome spinels makes it possible to obtain rigid fire-safe PUFs with high physico-mechanical properties. Fire-safe rigid filling PUFs, developed with the use of raw native materials, are recommended to be used for low-temperature thermal insulation of pipelines and technological equipment.

DOI: 10.22227/1997-0935.2018.12.1524-1532

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