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Aruova Lyazat Boranbaevna -
Kyzylorda State University Named after Korkyt Ata (Korkyt Ata KSU)
Doctor of Technical Sciences, Professor, Department of Architecture and Construction, Kyzylorda State University Named after Korkyt Ata (Korkyt Ata KSU), 29A Ayteke bi str., Kyzylorda, 120014, Kazakhstan;
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Dauzhanov Nabi Tokmurzaevich -
Kyzylorda State University named after Korkyt Ata
Candidate of Technical Sciences, Associate Professor,
87015660731, Kyzylorda State University named after Korkyt Ata, 29A Ayteke bi st., Kyzylorda, 120014, Kazakhstan;
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In the article, the authors consider heat and mass transfer inside reinforced concrete structures, and their impact on the mechanical properties of the latter.
The authors argue that humidity is an important factor of concrete hardening. As a rule, concrete-to-environment mass transfer, as well as the mass transfer inside concrete products, cause fast dehydration in the course of hardening, thus, leading to the insufficiency of strength. This phenomenon may be exemplified by prefab concrete products hardened in the hot and dry climate. The findings of the authors constitute a simple though efficient solution that consists in the employment of solar chambers equipped with an intermediate, or supplementary, heat carrier. Solar chambers are to be installed inside production premises.
Reinforced concrete products manufactured in accordance with the technology proposed by the authors feature high strength and durability. The concrete structure and properties (namely, compressive strength, tensile strength, modulus of elasticity and cold resistance) even exceed those of the concrete products hardened within 28 days in the regular temperature and humidity environment.
Theoretical principles and experimental research findings of the authors have been invested into the year-round technology of manufacturing of reinforced concrete products inside production premises, where products are treated by the solar energy and a supplementary source of energy. The concrete mix is poured into the form and compacted there; thereafter, the product surface is smoothed. Immediately after that a cover is fixed onto the form and tightly attached to the form walls. The process is to be initiated at 8 a.m. to maximize the period of solar energy consumption and to accelerate the process of concrete hardening.
DOI: 10.22227/1997-0935.2012.10.142-146
References
- Abhat A., Aboul–Enein S., Malatidis N. Heat-of-fusion Storage Systems for Solar Heating Applications in Lifter, no. 132, pp. 157—172.
- Cease M.E., White D.H. Emulsification of Thermal Energy Storage Materials in an Immiscible Fluid. International Journal of Energy Resources. 1983, no. 2, vol. 7, p. 25.
- Lu Changgeng. Industrial Production of Concrete Components in China. Betonwerk+Fertigteil-Technik (Concrete Precasting Plant and Technology), 1986, no. 5, p. 56.
- Malhotra V.M. In-place Evaluation of Concrete. Jour. of Constr. Div. Proc. of Am. Soc. of Civ. Engr. 1975, vol. 101, p. 45.
- Krylov B.A., Zasedatelev I.B., Malinskiy E.N. Izgotovlenie sbornogo zhelezobetona s primeneniem gelioform [Production of Prefab Reinforced Concrete Using Solar Hardening Forms]. Beton i zhelezobeton [Concrete and Reinforced Concrete]. 1984, no. 3, pp. 17—18.
- Krylov B.A., Chkuaselidze L.G., Topil’skiy G.V., Rybasov V.P. Vododispersionnye plenkoobrazuyushchie sostavy dlya betona v usloviyakh sukhogo zharkogo klimata [Water-dispersible Film-forming Concrete Compositions in Hot Dry Climates]. Beton i zhelezobeton [Concrete and Reinforced Concrete]. 1992, no. 6, p. 15.
- Krylov B.A., Zvezdov A.I. Vliyanie temperatury na ego strukturu i tverdenie [Temperature Influence on Concrete Structure and Hardening]. International Symposium in Japan E&FN Spook. 1995, vol. 2, pp. 917—925.
- Abhat A. Low Temperature Latent Heat Thermal Energy Storage. Heat Storage Materials. Solar Energy. 1983, no. 4, vol. 30, p. 65.
- Commission 42-CEA. Properties Set Concrete at Early Ages. State-of-the-art-report. Materiaux et Constructions. 1981, no. 84, vol. 14, p. 15.
- Kalt A.C. Speicherung Thermischer Energie in Anlagen dur Nulzung der Sonnenenergie. Oel+Gasfeuerung. 1980, no. 11, vol. 25, p. 55.
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Askadskiy Andrey Aleksandrovich -
Moscow State University of Civil Engineering (MGSU)
Doctor of Chemical Sciences, Honoured Scientist of the Russian Federation, Professor,
8 (495) 287-49-14, ext. 3143, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation.
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Popova Marina Nikolaevna -
Moscow State University of Civil Engineering (MGSU)
Doctor of Chemical Sciences, Professor
8 (495) 287-49-14, ext. 3076, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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Volodina Aleksandra Evgen'evna -
Moscow State University of Civil Engineering (MGSU)
postgraduate student,
8 (495) 287-49-14, ext. 3143, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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Polymeric materials are widely used in construction. The properties of polymeric construction materials vary to a substantial extent; their durability, thermal stability, frost resistance, waterproof and dielectric properties are particularly pronounced. Their properties serve as the drivers of the high market demand for these products. These materials are applied as finishing materials, molded sanitary engineering products and effective thermal insulation and water proofing materials.
The authors analyze the influence of the chemical structure and structural features of polymers on their properties. The authors consider flow and vitrification temperatures of polymers. These temperatures determine the parameters of polymeric products, including those important for the construction process.
The analysis of influence of concentration of the plasticizer on the vitrification temperature is based on the two basic theories. In accordance with the first one, reduction of the vitrification temperature is proportionate to the molar fraction of the injected plasticizer. According to the second concept, reduction of the vitrification temperature is proportionate to the volume fraction of the injected solvent. Dependencies of the flow temperature on the molecular weight and the molar fraction of the plasticizer are derived for PVC. As an example, two plasticizers were considered, including dibutyl sebacate and dioctylftalatalate. The basic parameters of all mixtures were calculated through the employment of "Cascade" software programme (A.N. Nesmeyanov Institute of Organoelemental Connections, Russian Academy of Sciences).
DOI: 10.22227/1997-0935.2012.10.147-153
References
- Askadskiy A.A., Matveev Yu.I. Khimicheskoe stroenie i fizicheskie svoystva polimerov [The Chemical Structure and Physical Properties of Polymers]. Moscow, Khimiya Publ., 1983. 248 p.
- Tager A.A. Fiziko-khimiya polimerov [Physical Chemistry of Polymers]. Moscow, Nauchnyy mir publ., 2007. 573 p.
- Askadskii A.A. Computational Materials Science of Polymers. Cambridge, Cambridge International Science Publishing, 2003, 650 p.
- Askadskiy A.A., Tishin S.A., Kazantseva V.V., Kovriga O.V. O mekhanizme deformatsii teplostoykikh aromaticheskikh polimerov (na primere poliimida) [About the Mechanism of Deformation of Heatresistant Aromatic Polymers (Exemplifi ed by Polyimide)]. Vysokomolekulyarnykh soedineniya [Macromolecular Compounds]. 1990, vol. 32, series a, no. 12, pp. 2437—2445.
- Odinokova I.A., Shevelev A.Yu., Zelenev Yu.V. Prognozirovanie mekhanicheskikh svoystv chastichno-kristallicheskikh polimerov po ikh teplofizicheskim kharakteristikam [Forecasting of Mechanical Properties of Semicrystalline Polymers Based on Their Thermalphysic Characteristics]. Plasticheskie massy [Plastic Masses]. 1988, no. 3, pp. 25—26.
- Prokopchuk N.R., Tolkach O.Ya., Paplevko I.G. O temperaturnoy zavisimosti energii aktivatsii destruktsii plastmass, volokon i rezin [About the Temperature Dependence of the Energy of Activation of Decomposition of Plastic Masses, Fibres and Rubber]. Reports of National Academy of Sciences of Belarus, 1998, vol. 42, no. 5, pp. 67—71.
- Bicerano J. Prediction of Polymers Properties. New-York, Marcel-Dekker Inc., 1996. pp. XVII+528.
- Askadskiy A.A., Popova M.N., Pakhneva O.V. Struktura i svoystva vtorichnykh poliolefinov [Structure and Properties of Secondary Polyolefines]. Collected works of International Scientific Conference “Integration, Partnership and Innovations in Civil Engineering Sciences and Education”]. Moscow, MGSU Publ., vol. 2, 2011. pp. 3—7.
- Askadskiy A.A., Popova M.N., Solov’eva E.V., Popov A.V. Poluchenie i svoystva vtorichnogo polivinilkhlorida [Recovery and Properties of Recycled Polyvinylchloride]. Collected works of International Scientific Conference “Integration, Partnership and Innovations in Civil Engineering Sciences and Education]. Moscow, MGSU Publ., vol. 2, 2011. pp. 8—11.
- Popova M.N. Tekhnologiya izgotovleniya i fiziko-khimicheskie kharakteristiki stroitel’nykh materialov na osnove vtorichnogo PVKh [Production Technology and Physicochemical Characteristics of Construction Materials Made of Recycled PVC]. Konstruktsii iz kompozitsionnykh materialov [Structures Made of Composite Materials]. 1998, no. 3.
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Gorshkov Pavel Vladimirovich -
Ivanovo State University of Architecture and Civil Engineering (ISUACE)
postgraduate student, Department of Engineering Structures, Ivanovo State University of Architecture and Civil Engineering (ISUACE), 20 8ogo Marta St., Ivanovo, 153037, Russian Federation;
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Non-autoclaved foam concrete is an advanced thermal insulation material. Until recently, foam concrete production has been based on separate preparation of foam and solution, followed by their blending in a mixer. The situation changed when high-quality synthetic foaming agents and turbulence cavitation technology appeared on the market. Every model provides a dependence between the foam concrete strength and the water-to-cement ratio. According to the water-cement ratio we can distinguish strong concrete mixtures (with the water-to-cement ratio equal to 0.3…0.4) and ductile ones (with the water-to-cement ratio equal to 0.5…0.7). Strong concrete mixtures are more durable. The lower the water-to-cement ratio, the higher the foam concrete strength.
However super-plastic substances cannot be mixed by ordinary turbulent mixers. Foam concrete produced using the turbulence cavitation technology needs air-entraining, its intensity being dependent on several factors. One of the main factors is the amount of free water, if it is insufficient, the mixture will not be porous enough. A researcher needs to identify the optimal water-to-cement ratio based on the water consumption rate. Practical production of prefabricated concrete products and structures has proven that the reduction of the water-to-cement ratio improves the strength of the product. The task is to find the water-to-cement ratio for the foam concrete mixture to be plastic enough for air entraining. An increase in the ratio causes loss in the strength. The ratio shall vary within one hundredth points. Super-plasticizers are an alternative solution.
DOI: 10.22227/1997-0935.2012.10.154-158
References
- Babkov V.V., Bazhenov Yu.M., Bykova A.A. Tsementy, betony, stroitel’nye rastvory i sukhie smesi [Cements, Concretes, Mortars and Dry Mixes]. St.Petersburg, NPO Professional Publ., 2007, Part I, 804 p.
- GOST 25485—89. Betony yacheistye tekhnicheskie usloviya [Cellular Concretes. Specifi cations].
- Gorshkov P.V. Penobeton i ego rol’ v sovremennom stroitel’stve [Foam Concrete and Its Role in Contemporary Construction]. Informatsionnaya sreda VUZa [Information Environment of Institutions of Higher Education]. Ivanovo, 2011, no. 17, pp. 507—510.
- Spravochnik stroitelya. Stroitel’naya tekhnika, konstruktsii i tekhnologii [Builder’s Reference Book. Machinery, Structures and Technologies]. Moscow, 2007, Tekhnosfera Publ., vol. 1, 520 p.
- Kholmyanskiy M.M. Beton i zhelezobeton: deformativnost’ i prochnost’ [Concrete and Reinforced Concrete: Deformability and Strength]. Moscow, Stroyizdat Publ., 1997, 576 p.
- Merkin A.P., Zayfman M.I. Seriya 8. Promyshlennost’ avtoklavnykh materialov i mestnykh vyazhushchikh [Series 8. Production of Autoclaved Materials and Local Binders]. Moscow, VNIIESM Publ., 1982, no. 2.
- Muradov E. G. Materialy dlya prigotovleniya betonnoy smesi i stroitel’nogo rastvora [Materials for Preparation of a Concrete Mix and Building Mortar]. Moscow, Vyssh. shk. publ., 1987, 110 p.
- Ruzhinskiy S.I. Vse o penobetone [Everything about Foam Concrete]. St.Petersburg, Stroy Beton Publ., 2006, 630 p.
- Evdokimov N.I., Matskevich A.F., Sytnik V.S. Tekhnologiya monolitnogo betona i zhelezobetona [Technology of In-situ Concrete and Reinforced Concrete]. Moscow, Vyssh. shk. publ., 1980, 355 p.
- Nevill’ A.M. Svoystva betona [Properties of Concrete]. Moscow, Izd-vo literatury po stroitel’stvu publ., 1972, 344 p.
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Grishina Аnna Nikolaevna -
Moscow State University of Civil Engineering (MGSU)
Candidate of Technical Sciences, Junior Researcher, Scientific and Education Centre for Nanotechnologies,
8 (499) 188-04-00, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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Korolev Evgeniy Valer'evich -
Moscow State University of Civil Engineering (MGSU)
Vice-rector for Academic Affairs, Director, Scientific and Educational Centre for Nanotechnologies,
8 (499) 188-04-00, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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The authors present their methodology of synthesis of a nano-scale additive designated for the stabilization of synthetic foaming agents. The nano-scale admixture is composed of iron hydroxide (III) sol and aqueous sodium hydro silicates (water glass). Besides the above method, the topological structural model of the nano-scale additive is proposed. The additive stability was assessed upon its one-day storage (with the foaming agent added), and the assessment data are provided in the article. The authors have discovered that it is advisable to use an iron chloride solution in the concentration of 1 % to manufacture the iron hydroxide (III) sol.
The authors have also discovered that the rate of jellification goes up in the process of injecting the foaming agent into the foam that contains the nano-scale admixture developed by the authors. Dependence between the amount of sodium hydro silicate and the viscosity of the system composed of the water glass and the sol of iron hydroxide (III) is examined in detail. The authors have identified that the average water glass viscosity curve demonstrates an extreme nature. The additive is used for the stabilization of the foam generated by synthetic foaming agents. The injection of the proposed additive improves foam stability. It is noteworthy that this positive result is free from any negative side effects.
DOI: 10.22227/1997-0935.2012.10.159-165
References
- Svatovskaya L.B., Sycheva À.Ì., Eliseeva N.N. Patent ¹ 2377207 Composite Admixture. Applicant and patentee: St.Petersburg State University of Railroad Engineering. Date of publication: 27.12.2009.
- Svatovskaya L.B., Sycheva À.Ì., Eliseeva N.N. Patent ¹ 2400443 Composite Admixture. Applicant and patentee: St.Petersburg State University of Railroad Engineering. Date of publication: 27.09.2010.
- Svatovskaya L.B., Sycheva À.Ì., Eliseeva N.N.. Patent ¹ 2393127 Composite Admixture for Foam Concretes. Applicant and patentee: St.Petersburg State University of Railroad Engineering. Date of publication: 27.06.2010.
- Eliseeva N.N. Penobetony neavtoklavnogo tverdeniya na osnove dobavok nanorazmera [Non-Autoclaved Foam Concretes with Nano-scale Admixtures]. St.Petersburg, 2010, 22 p.
- Lebedeva Ò.À. Yacheistye stenovye materialy na osnove mineralizovannykh pen iz zhidkogo stekla [Porous Walling Materials Made of Mineralized Water Glass Foams]. Bratsk, 2004, 201 p.
- Svatovskaya L.B., Sycheva A.M., Eliseeva N.N. Povyshenie kachestva neavtoklavnogo betona dobavkami nanorazmera [Improvement of the Non-autoclaved Foam Concrete Quality by Nano-scale Additives]. Nanotekhnologii v stroitel’stve [Nanotechnologies in Civil Engineering]. 2011, no. 1, pp. 50—62. Available at: http://nanobuild.ru.
- Svatovskaya L.B., Sycheva À.Ì., Eliseeva N.N. Patent ¹ 2443647 Composite Admixture for Foam Concretes. Applicant and patentee: St.Petersburg State University of Railroad Engineering. Date of publication: 27.02.2012.
- Svatovskaya L.B., Solov’eva V.Ya., Stepanova I.V., Korobov N.V., Starchuk D.S., Belyaev P.V., Chertkov M.V., Ivanova A.Y. Patent ¹ 2433099 High-strength Concrete. Applicant and patentee: St.Petersburg State University of Railroad Engineering. Date of publication: 10.11.2011.
- Komokhov P.G. Zol’-gel’ kak kontseptsiya nanotekhnologii tsementnogo kompozita, struktura sistemy i puti ee realizatsii [Sol-gel as a Concept of Nanotechnology of a Cement Composite Material. Structure of the System and Methods of Its Implementation]. Available at: http://rudocs.exdat.com/docs/index-319653.html. Date of access: 12.06.2012.
- Voyutskiy S.S. Kurs kolloidnoy khimii [A Course of Colloid Chemistry]. Moscow, Khimiya Publ., 1975, 512 p.
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Korolev Evgeniy Valer'evich -
Moscow State University of Civil Engineering (MGSU)
Doctor of Technical Sciences, Professor, Director of Research and Educational Centre for Nanotechnologies,
8 (499) 188-04-00, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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Beregovoy Vitaliy Aleksandrovich -
Penza State University of Architecture and Civil Engineering (PSUAC)
8 (8412) 9-29-501, Penza State University of Architecture and Civil Engineering (PSUAC), 28 G. Titova St., Penza, 440028, Russian Federation;
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Kostin Dmitriy Sergeevich -
Penza State University of Architecture and Civil Engineering (PGUAS)
postgraduate student, Department of Building Materials,
8 (8412) 92-94-10, Penza State University of Architecture and Civil Engineering (PGUAS), 28 Titova St., Penza, 440028, Russian Federation;
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The subject of the research is the influence of the type of Portland cement, as well as the nature and concentration of additives that represent electrolytes and polymers, onto the foam stability. The project is implemented within the framework of the research of foamed ceramic. Detailed explanation of the influence pattern is provided.
The research performed by the authors has generated the following findings. Besides the rheological properties of the solution, chemical interaction between the mix components must be taken into account in the course of development of the best foamed ceramic mix composition, as chemical processes produce a substantial influence onto the foam stability. Polymer additives based on liquid carbamyde-formaldehyde and polyacrylamide substantially improve the quality of the foam mineralized by the particles of the cement binder. They also assure the foam stability rate sufficient for the formation of a high-quality foamed material.
DOI: 10.22227/1997-0935.2012.10.166-170
References
- Shakhova L.D. Nekotorye aspekty issledovaniy strukturoobrazovaniya yacheistykh betonov neavtoklavnogo tverdeniya [Some Aspects of Research of Structurization of the Non-autoclaved Foamed Concrete]. Stroitel’nye materialy [Construction Materials], 2003, no. 2 (The Supplement), pp. 4—7.
- Beregovoy V.A., Proshina N.A., Korolev E.V., Beregovoy A.M., Bolotnikova O.V. Zharostoykie penobetony [Hear-resistant Foamed Concretes]. Penza, PGUAS Publ., 2007, 111 p.
- Gorin V.M., Sukhov V.Yu., Nekhaev P.V., Khlystov A.I., Riyazov R.T. Legkiy zharostoykiy beton yacheistoy struktury [Lightweight Heat-resistant Concrete That Has a Foamed Structure]. Stroitel’nye materialy [Construction Materials], 2003, no. 8, pp. 17—19.
- Beregovoy V.A., Korolev E.V., Bazhenov Yu.M. Effektivnye teploizolyatsionnye penokeramobetony [Effective Heat-insulating Foamed Ceramic Concretes]. Moscow, MGSU Publ., 2011, 264 p.
- Tikhomirov V.K. Peny. Teoriya i praktika ikh polucheniya i razrusheniya [Foams. Theory and Practice of Generation and Destruction]. Moscow, Khimiya Publ., 1975, 264 p.
- Kondo R., Daymon M. Fazovyy sostav zatverdevshego tsementnogo testa [Phase Composition of the Cured Cement Grout]. VI Mezhdunarodnyy kongress po khimii tsementa [6th International Congress on Cement Chemistry]. Moscow, 1976, book 1, vol. 2, pp. 244—258.
- Kuznetsova T.V. Alyuminatnye i sul’foalyuminatnye tsementy [Aluminate and Sulfoaluminate Cements]. Moscow, Stroyizdat Publ., 1986, 208 p.
- Kruglyakov P.M., Ekserova D.R. Pena i pennye plenki [Foam and Foam Films]. Moscow, Khimiya Publ., 1990, 432 p.
- Velichko E.G., Komar A.G. Retsepturno-tekhnologicheskie problemy penobetona [Problems of the Foamed Concrete Formulation and Technology]. Stroitel’nye materialy [Construction Materials]. 2004, no. 3, pp. 27—31.
- Lotov V.A., Mitina N.A. Vliyanie dobavok na formirovanie mezhporovoy peregorodki v gazobetone neavtoklavnogo tverdeniya [Influence of Additives onto Formation of Interpore Partitions in the Non-autoclaved Foamed Concrete]. Stroitel’nye materialy [Construction Materials]. 2003 (The Supplement), no. 3, pp. 2—6.
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Panfilova Marina Ivanovna -
Moscow State University of Civil Engineering (MGSU)
Candidate of Chemical Sciences, Associate Professor, Department of Physics, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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Ustinova Marina Vladimirovna -
Moscow State University of Railroad Engineering (MIIT)
Senior Lecturer, Department of Safety of the Technosphere,
8 (495) 799-95-50, Moscow State University of Railroad Engineering (MIIT), 22/2 Chasovaya St., Moscow, 125993, Russian Federation;
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Zubrev Nikolay Ivanovich -
Moscow State University of Railroad Engineering (MIIT)
Candidate of Technical Sciences, Professor, Department of Safety of the Technosphere,
8 (495) 799-95-50, Moscow State University of Railroad Engineering (MIIT), 22/2 Chasovaya St., Moscow, 125993, Russian Federation;
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Present-day methods of recovery of used wooden railway ties, including burial, chemical neutralization, gasification and subsequent burning, utilization in the capacity of composite materials, are expensive and unsafe for the environment. The authors propose a new method of their utilization. Ash generated in the course of their burning may replace a portion of cement in composite solutions and act as an additive to grouting mortars designated for the filling of the annulus space of manifold tunnels. The chemical composition of the ash was identified by the x-ray method applied to three samples taken during various periods of time from out of a dry-type dust collector.
The level of human health/environmental hazard of the ash is based on its chemical composition. Changes in the rheological properties of composite solutions that contained concrete fractions, various ratios of ash, and 5% of liquid glass were studied in the course of the research. The experiments have proven that in the event of replacement of 20% of cement by ash, the strength of the composite solution is approximately the same as the one of the benchmark sample; therefore, this ash content ratio is deemed acceptable. The finding demonstrate that the ash has no toxic effect, and the ecological safety of this solution is thus confirmed. The authors have proven that 20% of cement may be replaced by the ash generated in the course of burning of waste railway ties.
DOI: 10.22227/1997-0935.2012.10.171-177
References
- Gonopol’skiy A.M., Dygan M.M., Timofeeva A.A. Nekotorye fiziko-khimicheskie svoystva zoloshlakovykh otkhodov musoroszhigatel’nykh zavodov [Some Physicochemical Properties of Ash and Slam Waste Products of Waste Burning Plants]. Ekologiya i promyshlennost’ Rossii [Ecology and Industry of Russia]. 2008, no. 7, pp. 36—39.
- Makarova E.I., Sycheva A.M. Novye ekozashchitnye tekhnologii na zheleznodorozhnom transporte [New Ecological Technologies in Railroad Transport]. Moscow, Centre for Training and Methodology of the Railroad Transport Network. 2007, p. 13.
- Gubanov A.V. Utilizatsiya derevyannykh shpal: metody i vozmozhnye resheniya [Recycling of Wooden Cross Ties: Methods and Potential Solutions]. Put’ i putevoe khozyaystvo [Railroads and Railroad Economy]. 2009, no. 10, pp. 22—30.
- Lyapidevskiy B.V., Nikitin A.V., Rodina G.P., Badamshin S.O. In”ektsionnye sostavy dlya zablochnogo i zatrubnogo prostranstva kollektornykh tonneley [Injections for the Annulus Space of Manifold Tunnels]. Nauka — Moskovskomu stroitel’stvu. Sb. tekhnicheskoy informatsii [Collection of technological information “Research Contribution to the Moscow Construction Industry”]. 2008, no. 2, pp. 52—53.
- Ustinova M.V., Zubrev N.I. Ispol’zovanie letuchey zoly v in”ektsionnykh rastvorakh [Adding Flue Ash into Injections]. Collected papers of the 2nd International Scientific and Practical Conference “Relevant Problems of Economic, Social and Ecological Safety of the Volga Region”. Moscow, MIIT Publ., 2009, pp. 135—140.
- Ustinova M.V., Zubrev N.I. Bentonity dlya in”ektsionnykh rastvorov [Bentonites for Injections]. Collected papers of the 3d International Scientific and Practical Conference “Relevant Problems of Economic, Social and Ecological Safety of the Volga Region”. Moscow, MIIT ROAT Publ., 2009, pp. 44—49.
- Ustinova M.V., Zubrev N.I. Ispol’zovanie zoly musoroszhigatel’nogo zavoda v transportnom stroitel’stve [Use of Combustion Plant Ash in Railroad Engineering]. Collection of Materials of the 3d International Scientific and Practical Conference of Students and Young Scientists “Problems of Life Safety and Industrial Ecology”. Ul’yanovsk, UlGTU Publ., 2010, pp. 46—49.
- Ustinova M.V., Zubrev N.I. Modifi katsiya reologicheskikh svoystv bentonitovykh suspenziy [Modification of Rheological Properties of Bentonite Suspensions]. Collection of works of the 4th Interuniversity Scientific and Practical Conference “Relevant Problems of Economic, Social and Environmental Security of the Volga Region”. Kazan, MIIT Kazan branch, 2011, pp. 20—26.
- Ustinova M.V., Zubrev N.I., Aksenov V.A., Medvedev V.M. Ispol’zovanie zoly ot szhiganiya otrabotannykh derevyannykh shpal na termicheskoy ustanovke po obezvrezhivaniyu otkhodov [Feeding Waste Wooden Tie Ash into the Thermal Decontamination Machine]. Setevoe soveshchanie rukovoditeley prirodookhrannykh podrazdeleniy zheleznykh dorog «Problemy kompleksnoy utilizatsii otkhodov i puti ikh resheniya». Tezisy dokladov. [Problems of Comprehensive Recycling and Methods of Their Resolution. Network meeting of executives of nature protection departments of railroad administrations. Abstracts of reports.]. Kaliningrad, 2011, pp. 174—176.
- Aksenov V.A., Zubrev N.I., Ustinova M.V. Rasshirenie oblasti ispol’zovaniya zoly ot utilizatsii otrabotannykh derevyannykh shpal [New Areas of Application of Wooden Tie Ash]. Nauka i tekhnika transporta [Transport-related Research and Machinery]. 2011, no.3, pp. 12—14.
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Panfilova Marina Ivanovna -
Moscow State University of Civil Engineering (MGSU)
Candidate of Chemical Sciences, Associate Professor, Department of Physics, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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Fomina Marina Vasil'evna -
Moscow State University of Civil Engineering (MGSU)
Candidate of Physical and Mathematical Sciences, Professor, Department of Physics, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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Use of a special injection aimed at the partial replacement of cement by ash generated in the course of combustion of waste wooden crossties may solve two problems: recycling of a toxic
by-product generated in the course of combustion of crossties, and reduction of the cement consumption rate. The authors have identified that ash added into the injection does not cause any deterioration of the mortar strength; rather, it assures its structural stability and prevents any leaching of heavy metals that it contains. The authors have identified that adding 20 to 26 % of flue ash into the injection reduces the mortar hardening time by 30 %, while the strength of the mortar that has 20 % of ash is almost equal to the one of the benchmark sample. However, any higher ash content causes deterioration of the hardening strength of the mortar. Therefore, the authors have discovered that 20 % of the cement may be replaced by the ash generated in the course of combustion of waste crossties. This replacement is to be performed in the course of preparation of mortars, and it is aimed at the strengthening of the soil. This operation is to be performed in the incinerator to preserve the solution properties. This technology reduces the amount of hazardous by-products through their recycling.
DOI: 10.22227/1997-0935.2012.10.178-181
References
- Zubrev N.I., Panfilova M.I. Primenenie vspenennykh sistem pri stroitel’stve zheleznykh dorog [Application of Foamed Mortars in Railroad Engineering]. Bezopasnost’ dvizheniya poezdov. Tezisy dokladov nauchno-prakticheskoy konferentsii MGUPS (MIIT). [Railroad Traffic Safety. Proceedings of Scientific and Practical Conference. University of Railroad Engineering (MIIT)]. Moscow, MGUPS Publ., 2003, 35 p.
- Zubrev N.I., Goryaynova S.K., Panfilova M.I. Otverzhdennye glino-tsementnye rastvory v transportnom stroitel’stve [Hardened Clay-cement Mortars in the Transport Construction]. Vysshee professional’noe zaochnoe obrazovanie na zheleznodorozhnom transporte: nastoyashchee i budushchee. Sb. nauch. tr. po materialam mezhdunar. konf. [Collected works of International Conference “Higher Professional Distance Education in Railroad Engineering”]. Moscow, 2001, 287 p.
- Cheng Fa, Hou Gui. Synthesis and Properties of Sulfonated Starch as Super-plasticizer. Fine Chem. 2006, no. 7, vol. 23, pp. 711—716.
- Hollo J., Szejtli J. Die Saurehydrolyse der Starke. Berlin, Kl. Chem., Geol., Biol., 1965, no. 1, pp. 3—118.
- Miller J.N. Acid Hydrolysis and Other Lytic Reactions of Starch. Zitat, Bd. I., pp. 495—520.
- Zubrev N.I. Stabilizator dlya vspenennykh glinotsementnykh rastvorov [Stabilizer for Foamed Clay-cement Mortars. Izvestiya vuzov. Stroitel’stvo. [Bulletin of Institutions of Higher Education. Civil Engineering]. 1993, no. 2, pp. 53—56.
- Zubrev N.I., Goryaynova S.K., Panfilova M.I. Stabiliziruyushchiy kompleks issledovaniya fiziko-khimicheskikh svoystv stabilizatora neustoychivykh gruntov [Stabilization Methods. Research of Physicochemical Properties of a Stabilizer of Unstable Soils]. Aktual’nye problemy i perspektivy razvitiya zheleznodorozhnogo transporta. Sb. nauch. tr. po materialam V mezhvuzovskoy nauch.-metod. konf. [Collected papers of the 5th International Scientific and Methodological Conference “Relevant Problems and Prospects for Development of Railroad Transportation Systems”]. Moscow, 2000, RGOTUPS Publ., p. 94.
- Gonopol’skiy A.M., Dygan M.M., Timofeeva A.A. Nekotorye fi ziko-khimicheskie svoystva zoloshlakovykh otkhodov musoroszhigatel’nykh zavodov [Some Physicochemical Properties of Ash and Slam Waste Products of Waste Burning Plants]. Ekologiya i promyshlennost’ Rossii [Ecology and Industry of Russia]. 2008, no. 7, pp. 36—39.
- Ustinova M.V., Zubrev N.I. Ispol’zovanie letuchey zoly v in”ektsionnykh rastvorakh [Adding Flue Ash into Injections]. Aktual’nye problemy ekonomicheskoy i sotsial’no-ekologicheskoy bezopasnosti Povolzhskogo regiona. Sb. po materialam II Mezhvuzovskoy nauch.-prakt. konf. [ Collected papers of the 2nd International Scientific and Practical Conference “Relevant Problems of Economic, Social and Ecological Safety of the Volga Region”]. Moscow, MIIT Publ., 2009, pp. 135—140.
- Ustinova M.V., Zubrev N.I. Bentonity dlya in”ektsionnykh rastvorov [Bentonites for Injections]. Aktual’nye problemy ekonomicheskoy i sotsial’no-ekologicheskoy bezopasnosti Povolzhskogo regiona. Sb. po materialam III Mezhvuzovskoy nauch.-prakt. konf. [Collected papers of the 3d International Scientific and Practical Conference “Relevant Problems of Economic, Social and Ecological Safety of the Volga Region”]. Moscow, MIIT ROAT Publ., 2009, pp. 44—49.
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Semenov Vyacheslav Sergeevich -
Moscow State University of Civil Engineering (MGSU)
Candidate of Technical Sciences, Associate Professor, Department of Building Materials,
8 (495) 287- 49-14, ext. 3092, Moscow State University of Civil Engineering (MGSU), Office 515 ULK, 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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Oreshkin Dmitriy Vladimirovich -
Moscow State University of Civil Engineering (MGSU)
Doctor of Technical Sciences, Professor, Chair, Department of Building Materials,
8 (499) 183-32-29, Moscow State University of Civil Engineering (MGSU), Office 135 KMK, 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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Rozovskaya Tamara Alekseevna -
Moscow State University of Civil Engineering (MGSU)
postgraduate student, Department of Building Materials,
8 (495) 287-49-14, ext. 3092, Moscow State University of Civil Engineering (MGSU), Office 515 ULK, 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation;
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The authors provide their research findings concerning lightweight masonry mortars with hollow glass microspheres and antifreeze admixtures. These mortars are used in the construction of filler structures at negative temperatures. The application of multilayer filler structures causes reduction of their thermal homogeneity factor. Therefore, single-layer filler structures have the strongest potential. There is a need to employ lightweight masonry mortars to ensure the thermal homogeneity of structures made of lightweight concrete blocks. The masonry mortar that has traditional weight
reduction fillers (such as inflated pearlite, vermiculite etc.) demonstrate low strength properties, as such fillers have a high water content. Hollow glass (or ceramic) microspheres are known as efficient fillers for lightweight mortars. Multiple research undertakings contain information on the masonry mortar that has the following properties: average density of dry mortar - 450 kg/m3, thermal conductivity factor - 0.17 W/(m·°C), compressive strength at the age of 28 days - 3.2 MPa, water retention rate - over 90 %.
The climatic conditions of Russia determine the need to perform masonry works at negative temperatures. Adding antifreeze admixtures is an easy and cheap method that guarantees hydration of the Portland-cement at negative temperatures. The subject of this research covers masonry mortars that have a 15 % hollow glass microsphere content and antifreeze admixtures. Contemporary antifreeze admixtures are multifunctional. Therefore, traditional antifreeze admixtures such as sodium chloride, calcium chloride, sodium nitrite, sodium nitrate, sodium formate, potash were used in the research. The per-cent content of antifreeze admixtures was calculated. The following properties of masonry mortars with a 15 % content of hollow glass microspheres and antifreeze admixtures were identified: average mortar and mortar mixture density, setting time, water retention, compressive and bending strength, and water absorption. Standard research methods were employed.
Every mortar has an 8 cm mobility. The benchmark mixture has an average density of 1.085 kg/ m3, average cement stone density of 980 kg/m3, compressive strength at the age of 28 days - 19.8 MPa, water retention rate - 97 %, setting time - 4.5 hours.
The attention was driven to the strength analysis of mortars with hollow glass microspheres and antifreeze admixtures at positive and negative temperatures. The authors proved that antifreeze admixtures demonstrated a negative influence on the strength and setting time of the mortar if hardened at 20 °C. The strength of mortars with antifreeze admixtures was below that of the benchmark mortar. Mortars that had sodium nitrite and sodium chloride demonstrated better results, while the mortar with calcium chloride showed the lowest strength.
Sodium nitrite, sodium formate and potash were mostly efficient at negative temperatures. The mortar with sodium nitrite demonstrated the highest strength, as it had hardened at the positive temperature. Optimal mixtures for the temperature of -10 °C were developed by the math planning method.
The results of the microstructure analysis for optimized mixtures are provided in the article. The finding of the authors are that at the temperature of -10 °С the following mixtures have the best properties: lightweight masonry mortars with hollow glass microspheres and sodium nitrite (7 %), or sodium formate (5 %), or potash (7 %) with a setting retarder added.
DOI: 10.22227/1997-0935.2012.10.182-190
References
- Kirillov K.I. Sverkhlyegkie tsementnye kladochnye i tamponazhnye rastvory [Superlight Cement Masonry and Grouting Mortars]. Moscow, MGSU Publ., 2006, 159 p.
- Kozlov V.V. Sukhie stroitel’nye smesi [Dry Packs]. Moscow, ASV Publ., 2000.
- Korneev V.I., Zozulya P.V. Sukhie stroitel’nye smesi [Dry Packs]. Moscow, RIF Stroymaterialy Publ., 2010, 320 p.
- Oreshkin D.V., Belyaev K.V., Semenov V.S. Vysokokachestvennye stroitel’nye i tamponazhnye rastvory s polymi steklyannymi mikrospherami [High-quality Building and Grouting Mortars with Hollow Glass Microspheres]. Promyshlennoe i grazhdanskoe stroitel’stvo [Industrial and Civil Engineering]. 2010, no. 10, pp. 53—58.
- Semenov V.S. Effektivnye oblegchyennye kladochnye i tamponazhnye rastvory dlya surovykh klimaticheskikh usloviy [Effi cient Light-weight Masonry and Grouting Mortars for Severe Climatic Conditions]. Moscow, MGSU Publ., 2011, 242 p.
- Semenov V.S. Protivomoroznye dobavki dlya oblegchyennykh tsementnykh sistem [Antifreeze Compounds for Light-weight Cement Systems]. Stroitel’nye materialy [Construction Materials]. 2011, no. 5, pp. 16—19.
- GOST 28013—98. Rastvory stroitel’nye. Obshchie tekhnicheskie usloviya. [State Standard 28013—98. Construction Mortars. General Specifications]. Moscow, MNTKS Publ., 1998.
- GOST 5802—86. Rastvory stroitel’nye. Metody ispytaniy. [State Standard 5802–86. Mortars. Testing Methods]. Moscow, Minstroy Rossii, 1998.
- SP 82–101—98. Prigotovlenie i primenenie rastvorov stroitel’nykh. [Construction Regulations 82–101–98. Preparation and Application of Building Mortars]. Moscow, Gosstroy Rossii Publ., 1998.
- Mironov S.A., Lagoyda A.V. Betony, tverdeyushchie na morose [Concretes That Harden in the Frost]. Moscow, Stroyizdat Publ., 1975, 266 p.
- GOST 3045—2008. Dobavki dlya betonov i stroitel’nykh rastvorov. Opredelenie i otsenka effektivnosti [State Standard 30459–2008. Admixtures for Concretes and Mortars. Identification and Efficiency Assessment]. Moscow, Standartinform Publ., 2010.
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Tarasov Roman Viktorovich -
Penza State University of Architecture and Civil Engineering (PGUAS)
Candidate of Technical Sciences, Associate Professor, Dean of the Faculty of Technology,
8 (8412) 92-94-78, Penza State University of Architecture and Civil Engineering (PGUAS), 28 G. Titova St., Penza, 440028, Russian Federation;
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Makarova Ludmila Victorovna -
Penza State University of Architecture and Civil Engineering (PGUAS)
Candidate of Technical Sciences, Associate Professor,
8 (8412) 92-94-78, Penza State University of Architecture and Civil Engineering (PGUAS), 28 G. Titova St., Penza, 440028, Russian Federation;
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Satyukov Anton Borisovich -
Penza State University of Architecture and Civil Engineering (PGUAS)
volunteer postgraduate student,
8 (8412) 92-94-78, Penza State University of Architecture and Civil Engineering (PGUAS), 28 G. Titova St., Penza, 440028, Russian Federation;
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Korolev Evgeniy Valer'evich -
Moscow State University of Civil Engineering (MGSU)
Doctor of Technical Sciences, Professor, Adviser, Russian Academy of Architectural and Building Sciences (RAACS), director, Moscow State University of Civil Engineering (MGSU), 26 Yaroslavskoe shosse, Moscow, 129337, Russian Federation; +7-499-188-04-00;
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The status of nanotechnologies in material science predetermines development of nanotechnology-intensive products that demonstrate pre-set properties of modified materials. The presence of nano-size particles of substances makes it possible to benefit from their physical and chemical potential and to overcome some negative developments that accompany the structure formation process (at interphase boundaries). The barrier properties are variable, which is quite important in terms of the increase of the asphalt concrete durability. Production of a modifier (that has nano-particles of the pre-set chemical composition) to be added into asphalt concrete mixes is also of interest.
The authors present their findings concerning the nano-scale modifier that has a chemically inert component and a hydraulically active substance. The method of de-aggregation is used to produce the nano-scale modifier. By-products are often welcomed as mineral components of the asphalt concrete, as they reduce its cost.
The findings of the authors concerning the influence of the grinding mode on the integrated characteristics of the powder are presented in the paper. It is proven than dependence of integrated dispersion indicators is nonlinear due to processes leading to aggregation of mineral powder particles.
The analysis of the experimental data collected in the course of "wet" grinding proves that surface-active substances stimulate the process of grinding. The type and concentration of an additive that improves the grinding efficiency is also identified.
DOI: 10.22227/1997-0935.2012.10.191-198
References
- Rudenskiy A.V. Opyt stroitel’stva dorozhnykh asfal’tobetonnykh pokrytiy v raznykh klimaticheskikh usloviyakh [Construction of Asphalt Concrete Pavements in Various Climatic Conditions]. Moscow, Transport Publ., 1983, 64 p.
- Podol’skiy V.P., Erokhin A.V. Korrozionnaya ustoychivost’ asfal’tobetonov s ispol’zovaniem mineral’nogo poroshka iz uglerodsoderzhashchikh materialov [Corrosion Resistance of Asphalt Concretes: Using Mineral Powder of Carbonaceous Materials]. Nauchnyy Vestnik VGASU. Stroitel’stvo i arkhitektura. [Scientific Herald of VGASU. Construction and Architecture]. 2008, no. 1, pp. 249—252.
- Chernousov D.I., Podol’skiy Vl.P., Trufanov E.V. Issledovanie ustalostnoy dolgovechnosti asfal’tobetona na osnove shungitovogo mineral’nogo poroshka [Research of Fatigue Life of Asphalt Concrete That Contains Schungite Mineral Powder]. Nauchnyy Vestnik VGASU. Stroitel’stvo i arkhitektura. [Scientific Herald of VGASU. Construction and Architecture]. 2011, no. 1(21), pp. 75—80.
- Podol’skiy Vl.P., Chernousov D.I., Usachev S.M. Issledovaniya fiziko-mekhanicheskikh svoystv bitumno-shungitovogo vyazhushchego na skaniruyushchem mikroskope [Research of Physical and Mechanical Properties of Bituminous Binders through Employment of a Scanning Microscope]. Nauchnyy Vestnik VGASU. Stroitel’stvo i arkhitektura. [Scientific Herald of VGASU. Construction and Architecture]. 2010, no. 4(20), pp. 93—99.
- Chernousov D.I., Shcherbinina S.E. Obosnovanie vozmozhnosti primeneniya mineral’nogo poroshka iz shungita v asfal’tobetonnykh smesyakh [Feasibility of Adding Schungite Mineral Powder into Asphalt Concrete Mixes]. Nauka i tekhnika v dorozhnoy otrasli [Science and Technology in Road Building]. 2009, no. 2, pp. 34—35.
- Podol’skiy Vl.P., Bykova A.A., Chernousov D.I. Vliyanie shungitovogo mineral’nogo poroshka na ustoychivost’ struktury peschanogo asfal’tobetona v usloviyakh uvlazhneniya [Influence of Schungite Mineral Powder on Structural Stability of Sand Asphalt Concrete in Moisture Conditions]. Collected works of the First Russian Road Building Congress, 2009, pp. 219—222.
- Gezentsvey L.B. Asfal’tovyy beton iz aktivirovannykh mineral’nykh materialov [Bituminous Concrete Made of Activated Mineral Materials]. Moscow, 1971, 225 p.
- Korolev I.V. Model’ stareniya bitumnoy plenki na mineral’nykh zernakh v asfal’tobetone [Model of Aging of the Bitumen Film on Mineral Grains of Bituminous Concrete]. Izvestiya vuzov. Stroitel’stvo i arkhitektura. [News of Higher Education Institutions. Construction and Architecture]. 1981, no. 8, pp. 63—67.
- Official site of Scientific and Educational Centre “Nanotechnologies”. Available at: www.nocnt.ru. Date of access: 04.06.2012.